Reference - Detail
|Author||Tsuda M, Kasai Y, Komatsu K, Sone T, Tanaka M, Mikami Y, Kobayashi J.|
|Title||Citrinadin A, a novel pentacyclic alkaloid from marine-derived fungus Penicillium citrinum.|
[structure: see text] A novel pentacyclic alkaloid, citrinadin A (1), was isolated from the cultured broth of the fungus Penicillium citrinum, which was separated from a marine red alga, and the structure was elucidated by spectroscopic data. The relative stereochemistry of the pentacyclic core was assigned on the basis of NOESY data and (1)H-(1)H coupling constants, and the presence of an N,N-dimethyl-L-valine residue in 1 was determined by chiral HPLC analysis of the hydrolysate.
|MeSH||Alkaloids / chemistry* Alkaloids / isolation & purification* Chromatography, High Pressure Liquid Indole Alkaloids Molecular Structure Nuclear Magnetic Resonance, Biomolecular Penicillium / chemistry* Quinolizines / chemistry* Quinolizines / isolation & purification* Rhodophyta Valine / analogs & derivatives* Valine / chemistry Valine / isolation & purification|
|WOS Category||CHEMISTRY, ORGANIC|
|Pathogenic microorganisms||P. citrinum?|