RRC ID 15775
Author Tanioka Y, Miyamoto E, Yabuta Y, Ohnishi K, Fujita T, Yamaji R, Misono H, Shigeoka S, Nakano Y, Inui H, Watanabe F.
Title Methyladeninylcobamide functions as the cofactor of methionine synthase in a Cyanobacterium, Spirulina platensis NIES-39.
Journal FEBS Lett
Abstract To clarify the physiological function of pseudovitamin B(12) (or adeninylcobamide; AdeCba) in Spirulina platensis NIES-39, cobalamin-dependent methionine synthase (MS) was characterized. We cloned the full-length Spirulina MS. The clone contained an open reading frame encoding a protein of 1183 amino acids with a molecular mass of 132 kDa. Deduced amino acid sequences of the Spirulina MS contained critical residues identical to cobalamin-, zinc-, S-adenosylmethionine-, and homocysteine-binding motifs. The recombinant Spirulina enzyme showed higher affinity for methyladeninylcobamide than methylcobalamin as a cofactor. These results indicate that Spirulina cells can utilize AdeCba synthesized as the cofactor for MS.
Volume 584(14)
Pages 3223-6
Published 2010-7-16
DOI 10.1016/j.febslet.2010.06.013
PII S0014-5793(10)00503-X
PMID 20558164
MeSH 5-Methyltetrahydrofolate-Homocysteine S-Methyltransferase / chemistry 5-Methyltetrahydrofolate-Homocysteine S-Methyltransferase / genetics 5-Methyltetrahydrofolate-Homocysteine S-Methyltransferase / metabolism* Amino Acid Sequence Bacteria / genetics Bacteria / metabolism Cyanobacteria / genetics Cyanobacteria / metabolism* Inorganic Chemicals Molecular Sequence Data Organic Chemicals Protein Structure, Tertiary / genetics S-Adenosylmethionine / genetics S-Adenosylmethionine / metabolism Vitamin B 12 / analogs & derivatives Vitamin B 12 / genetics Vitamin B 12 / metabolism
IF 3.057
Times Cited 20
WOS Category BIOPHYSICS BIOCHEMISTRY & MOLECULAR BIOLOGY CELL BIOLOGY
Resource
General Microbes JCM 6427
Algae NIES-39