論文 - 詳細
RRC ID | 20349 |
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著者 | Yasumoto K, Nishigami A, Kasai F, Kusumi T, Ooi T. |
タイトル | Isolation and absolute configuration determination of aliphatic sulfates as the Daphnia kairomones inducing morphological defense of a phytoplankton. |
ジャーナル | Chem Pharm Bull (Tokyo) |
Abstract |
2,6-Dimethylheptyl sulfate (1) and 6-methyloctyl sulfate (3) were isolated from Daphnia pulex as the Daphnia kairomones that induced morphological defense of a freshwater phytoplankton Scenedesmus gutwinskii var. heterospina (NIES-802). The absolute stereochemistry at C2 of 1 was determined by (1)H-NMR analysis of the (R)-MTPA ester of alcohol 2. The absolute configuration at C6 of 3 was determined by Ohrui's method applied to alcohol 4. |
巻・号 | 54(2) |
ページ | 271-4 |
公開日 | 2006-2-1 |
DOI | 10.1248/cpb.54.271 |
PII | JST.JSTAGE/cpb/54.271 |
PMID | 16462083 |
MeSH | Alkanesulfonic Acids / chemistry* Alkanesulfonic Acids / isolation & purification Alkanesulfonic Acids / pharmacology* Animals Daphnia / chemistry* Heptanes / chemistry* Heptanes / isolation & purification Heptanes / pharmacology* Indicators and Reagents Magnetic Resonance Spectroscopy Molecular Conformation Scenedesmus / drug effects* Scenedesmus / ultrastructure Spectrometry, Mass, Fast Atom Bombardment Stereoisomerism Sulfates / chemistry* Sulfates / isolation & purification Sulfates / pharmacology* Sulfuric Acid Esters / chemistry* Sulfuric Acid Esters / isolation & purification Sulfuric Acid Esters / pharmacology* |
IF | 1.416 |
引用数 | 21 |
WOS 分野 | CHEMISTRY, MULTIDISCIPLINARY PHARMACOLOGY & PHARMACY CHEMISTRY, MEDICINAL |
リソース情報 | |
藻類 | NIES-802 |